Investigation of Electrocatalytic Applications of Various Advanced Nanostructured Alloys-An Overview

Abstract

Cyclic voltammetry (CV) is one of the advanced techniques used to determine various bioactive molecules, organic dyes, pesticides, veterinary drugs, heavy metals, toxic chemicals, etc. To determine all the above analytes, one needs an electrocatalyst for their electrochemical redox reaction. Many researchers have reported the use of metal nanomaterials, metal oxide nanomaterials, metal-organic frameworks, surfactants, polymers, etc., as modifiers in carbon paste electrodes to enhance their current response, stability, sensitivity, and repeatability. But some of the emerging, cost-effective, and highly efficient electrocatalysts are advanced nanostructured alloy powders. These advanced alloys are used as a modifier to determine various bioactive analytes. These alloy-modified carbon paste electrodes (MCPEs) show excellent selectivity, sensitivity, and stability due to their extraordinary electrochemical properties, as the compositional elements of most of the alloys belong to d-block elements in the periodic table, and these transition elements are famous for their brilliant electrocatalytic properties. The present review article mainly focuses on the determination of dopamine, AA (AA), uric acid, methylene blue, methyl orange, Rhodamine B, and the L-Tyrosine amino acid by various alloys like stainless steel, high-entropy alloys, and shape-memory alloys and how these alloys could change the perception of metallurgists and electrochemists in the future. These alloys could be potential candidates for the development of various electrochemical sensors because of their high porosity and surface areas.