An intramolecular phosphine-oxide stabilized germanium(iv) di-cation with enhanced Lewis acidity and catalytic applications

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dc.contributor.authorKumari, Akanksha
dc.contributor.authorPeddi, Balakrishna
dc.contributor.authorYıldız, Cem Burak
dc.contributor.authorMajumdar, Moumita
dc.contributor.authorYıldız, Cem Burak
dc.date.accessioned2025-10-18T10:04:53Z
dc.date.created2025
dc.date.issued2025
dc.departmentFakülteler, Mühendislik Mimarlık ve Tasarım Fakültesi, Temel Bilimler Bölümü
dc.description.abstractThis work reports the intramolecular phosphine-oxide stabilized tetra-coordinated germanium(iv) di-cation on an acenaphthene platform, 1iPrPO. Computational study shows that the positive charges and the acceptor orbitals are localized on the Ge site. 1iPrPO is Lewis super acidic, capable of catalysing hydrodefluorination reaction. 1iPrPO also catalyses hydrosilylation of electron-deficient aldehydes.
dc.description.sponsorshipSERB India [SPF/2022/000046, CRG/2022/000673]; UGC
dc.description.sponsorshipM. M. thanks SERB India SPF/2022/000046 and CRG/2022/000673 for financial support. A. K. thanks UGC for the fellowship. We thank Prof. Deepak Chopra from the Indian Instituteof Science Education and Research (IISER) Bhopal, India for hishelp in crystallography.
dc.identifier.doi10.1039/d5cc00250h
dc.identifier.endpage6509
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.issue35
dc.identifier.pmid40183800
dc.identifier.scopus2-s2.0-105002139465
dc.identifier.scopusqualityQ1
dc.identifier.startpage6506
dc.identifier.urihttps://doi.org/10.1039/d5cc00250h
dc.identifier.urihttps://hdl.handle.net/11772/20962
dc.identifier.volume61
dc.identifier.wosWOS:001458879900001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherRoyal Soc Chemistry
dc.relation.ispartofChemical Communications
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzWoS_20251016
dc.subject[No Keywords]
dc.titleAn intramolecular phosphine-oxide stabilized germanium(iv) di-cation with enhanced Lewis acidity and catalytic applications
dc.typeArticle
dspace.entity.typePublication
relation.isAuthorOfPublicationb6c70d5c-b8a2-449c-a6d9-23fbd389599b
relation.isAuthorOfPublication.latestForDiscoveryb6c70d5c-b8a2-449c-a6d9-23fbd389599b

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