Temperature-controlled formation of two Zn(II)-coordination polymers based on flexible o-phenylenediacetic acid and rigid 1,4-bis(imidazol-1-yl)benzene

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dc.contributor.authorSezer, Gunes Gunay
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorArici, Mursel
dc.contributor.authorErer, Hakan
dc.date.accessioned2025-10-18T13:22:53Z
dc.date.created2015
dc.date.issued2015
dc.departmentBartın Üniversitesi
dc.description.abstractTwo new coordination polymers with the same components, namely [Zn(mu-opda)(mu-dib)(0.5)(dib)](n) (1) and [Zn(mu(3)-opda)(mu-dib)(0.5)] (2), were synthesized under different temperatures and characterized by elemental analyses, IR spectroscopy, powder and single X-ray diffractions. The X-ray results showed that complex 1, synthesized at 120 degrees C, was a 1D ladder-like coordination polymer. When the reaction temperature was increased from 120 to 170 degrees C, a 2D coordination polymer (complex 2) was obtained with the sql topology. The o-pda ligand displayed different coordination modes in 1 and 2. Moreover, thermal, photoluminescence and topological properties of the synthesized complexes were studied in detail. (C) 2015 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [1649B031402373]; Eskisehir Osmangazi Universitesi - Turkey [201519029]
dc.description.sponsorshipThis work has been supported by The Scientific and Technological Research Council of Turkey (TUBITAK, No: 1649B031402373) and the Research Fund of Eskisehir Osmangazi Universitesi - Turkey by project Number: 201519029.
dc.identifier.doi10.1016/j.poly.2015.09.067
dc.identifier.endpage520
dc.identifier.issn0277-5387
dc.identifier.orcidErer, Hakan/0000-0003-3540-8797
dc.identifier.orcidYESILEL, Okan Zafer/0000-0002-2284-1578
dc.identifier.orcidArici, Mursel/0000-0001-8527-1587;
dc.identifier.scopus2-s2.0-84945947094
dc.identifier.scopusqualityQ1
dc.identifier.startpage514
dc.identifier.urihttps://doi.org/10.1016/j.poly.2015.09.067
dc.identifier.urihttps://hdl.handle.net/11772/22581
dc.identifier.volume102
dc.identifier.wosWOS:000367757100066
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzWoS_20251016
dc.subjectO-Phenylenediacetate
dc.subjectCoordination Polymer
dc.subjectTemperature Effect
dc.subjectPhotoluminescence
dc.subject1,4-Bis(Imidazol-1-Yl)Benzene
dc.titleTemperature-controlled formation of two Zn(II)-coordination polymers based on flexible o-phenylenediacetic acid and rigid 1,4-bis(imidazol-1-yl)benzene
dc.typeArticle
dspace.entity.typePublication

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