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dc.contributor.authorKorkmaz, Nesrin
dc.contributor.authorKaradağ, Ahmet
dc.date.accessioned2019-04-19T12:41:27Z
dc.date.available2019-04-19T12:41:27Z
dc.date.issued2014-07-05
dc.identifier.urihttp://hdl.handle.net/11772/1054
dc.description.abstractTwo novel cyanido-bridged bimetallic polymeric complexes, [Ni(hydeten)2Ag(CN)2] [Ag(CN) 2] H2O(C1) and [Cd2(hydeten)2Ag4(CN)8] H2O( C2) (hydeten: N-(2-hydroxyethyl)ethylenediamine) were synthesized and characterized by elemental, FT-IR, X-ray (C2), thermal and variable temperature magnetic measurement (C1) techniques. Their anticancer, antibacterial and antifungal effects were also investigated. The crystallographic analyses showed that C2 crystallizes in the monoclinic space group P21/c and shows a 3D 6,4 ladder-type polymeric chain in which the CdII centers are linked by [Ag(CN)2] units. The Ag Ag distance exhibits a short value of 3.1365(9) Å. It features a rare linear pentameric unit of [Ag(CN)2] ions assembled via d10–d10 interaction as building blocks. Both complexes exhibited outstanding antibacterial, antifungal and anticancer activities against ten different bacterial strains, two plant pathogenic fungi (Alternaria solani and Rhizoctonia solani) and four tumor cell lines (HT-29, HeLa, C6 and Vero), respectively.en_US
dc.description.sponsorshipScientific and Technical Research Council ofTurkey(TUBTAK,Grant TBAG-112T696;COST Action CM 2515) Gaziosmanpas- a University Research Foundation (Grant 2011/32)en_US
dc.language.isoengen_US
dc.publisherRoyal Society of Chemistryen_US
dc.relation.isversionof10.1039/c4nj00851ken_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectMetal complexesen_US
dc.subjectanticancer activityen_US
dc.subjectcytotoxic activityen_US
dc.subjectapoptosisen_US
dc.subjectsilver complexesen_US
dc.titleSynthesis and characterization of two novel dicyanidoargentate(I) complexes containing N-(2-hydroxyethyl)ethylenediamine exhibiting significant biological activityen_US
dc.typearticleen_US
dc.relation.journalNew Journal of Chemistryen_US
dc.contributor.departmentBartın Üniversitesi, Fen Fakültesi, Biyoteknoloji Bölümüen_US
dc.contributor.authorID0000-0002-7896-1042en_US
dc.identifier.volume2014en_US
dc.identifier.issue38en_US
dc.identifier.startpage4760en_US
dc.identifier.endpage4773en_US


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